基于2,5-二(4′-甲酰基苯基)苯乙烯的螺旋链光学活性聚合物的合成与表征

通过2,5-二溴苯乙烯与对甲酰基苯硼酸的Suzuki偶联反应得到2,5-二(4′-甲酰基苯基)苯乙烯.在催化剂量的冰乙酸存在下,与光学纯的(S)-(-)-α-甲基苄胺或(R)-(+)-α-甲基苄胺发生缩和反应,得到了一对手性非外消旋单体,(+)-2,5-二{4-′[(N-(S)-α-甲基苄亚胺基)次甲基]苯基}苯乙烯和(-)-2,5-二{4′-[(N-(R)-α-甲基苄亚胺基)次甲基]苯基}苯乙烯.以偶氮二异丁腈(AIBN)或过氧化苯甲酰(BPO)为引发剂,经自由基溶液聚合得到光学活性聚合物.比旋光度、紫外-可见吸收光谱以及圆二色光谱研究表明,聚合物主链可能形成了某一方向占优的稳定螺旋构象,且该螺旋构象的旋光方向与单体的旋光方向相反.聚合条件对聚合物的光学活性有很大影响,在极性较大的芳香族溶剂和较高温度下得到的聚合物具有和单体相差更大的比旋光度.侧基的手性基团脱除后,聚合物仍具有一定的旋光性,说明聚合过程中形成的螺旋手性具有一定的记忆效应.     

板模型中具广义边界条件的迁移算子的谱分析

在LP(1 P<∞)空间研究了板模型中一类带广义边界条件具各向异性、连续能量、均匀介质迁移算子的谱,证明了该迁移算子生成C0半群的D yson—Ph illips展开式的二阶余项在LP(1相似文献   

The automorphism group of Payne derived generalized quadrangles

We solve a long-standing open problem by proving that the automorphism group of any thick Payne derived generalized quadrangle with ambient quadrangle S a thick generalized quadrangle of order s, s?5 and odd, with a center of symmetry, is induced by the automorphism group of S.     

Representations, convolution square roots and spherical vectors

We extend results on square integrable representations of a locally compact group to subrepresentations of a representations induced from a character of a closed subgroup. We do so working in the framework of quotient representations of ∗-algebras.     

Automatic continuity and representation of group homomorphisms defined between groups of continuous functions

Let C(X,G) be the group of continuous functions from a topological space X into a topological group G with pointwise multiplication as the composition law, endowed with the uniform convergence topology. To what extent does the group structure of C(X,G) determine the topology of X? More generally, when does the existence of a group homomorphism H between the groups C(X,G) and C(Y,G) implies that there is a continuous map h of Y into X such that H is canonically represented by h? We prove that, for any topological group G and compact spaces X and Y, every non-vanishing C-isomorphism (defined below) H of C(X,G) into C(Y,G) is automatically continuous and can be canonically represented by a continuous map h of Y into X. Some applications to specific groups and examples are given in the paper.     

Propagation of Light in an Ensemble of Tripod Level Atoms

We study the propagation of a quantum probe light in an ensemble of tripod level atoms when the atoms are coupled to two other classical control fields. First we calculate the dispersion properties, such as susceptibility and group velocity, of the probe light within such an atomic medium under the case of three-photon resonance via the dynamical algebra method of collective atomic excitations. Then we calculate the dispersion of the probe light in the case that two classical control fields have the different detunings to the relative atomic transitions. Our results show that in both cases the phenomenon of electromagnetically induced transparency can occur. Especially under the second case, we can find two transparency windows for the probe light.     

群作用的几乎周期性与等度连续性

In this paper, a characterization of almost periodicity of topological transformation groups on uniform spaces is given. By searching the appropriate base for uniform structure, it is shown that the topological transformation group is topologically equivalent to an isometric one if it is uniformly equicontinuous.     

Homogeneous immunoassays

Applied Biochemistry and Biotechnology -     

晶体学与准晶体学点群的母子群关系

依据群论，得出了准晶体学点群的直积或半直积推导算式；依据结晶学理论，绘出了五角、八角、十角和十二角晶系各点群的极赤投影图.据此推导出了每一个准晶体学点群的全部最大子群，从而推导并绘制出了三维晶体学和准晶体学点群之间的母子群关系(60个点群的“家谱”).该“家谱”以最大子群链的图解形式直观地给出了每个点群的最小母群和最大子群. 关键词： 准晶体 晶体 点群 最大子群 最小母群 群链